You won't be getting 6 hours out of an RV-4, with only standard tanks. Or even any LR tanks I know of... At 32 USG (121L) capacity, and using my O-340's 24.2LPH, you've got 4.2 hours endurance before hitting your 18L fixed reserve. Even my -9 I would plan no more than 4:45, leaving around 21L on touchdown. FWIW, I would strongly recommend a -9 if you need cross-country but don't want aerobatic capability, but I am biased. Here's why:
36USG / 135L fuel capacity, greater than the -4, based on standard tanks on both.
A higher aspect ratio wing than the -4, which going by your 6 hour endurance requirement suggests you're doing serious cross-country regularly, so the -9 will be a lot more efficient up high.
The side-by-side aspect, meaning you can actually stretch out on said cross country. Sure it can be done in a -4, but if you're doing it regularly, why not enjoy the trip? Personal preference here, obviously, but I am 6'5...
The availability of 2 x long range tanks that fit behind the seats in the SBS models, that increase your total fuel capacity to 50USG / 189L for the -9, in turn taking your total endurance to 7.0 hrs before your 45 min fixed reserve.
Hotel Whiskey aviation also make LR tanks for the -4, but they're "installed" vs a more temporary fit that you get with Marvin's tanks (which can be permanently mounted too), so unless you built the -4, you'll likely have problems getting them signed off. But if you could do it, they are 4.1 USG a side, bringing your capacity to 40.2 USG for 5.5 hrs before hitting your fixed reserve, so you're still going to have to land halfway if you go for a -4 with the HW tanks.
The RV-4 is slightly faster on the same power, by about 8 smph, than my RV-9, but in saying that, I don't have the gear intersection fairings or NLG leg fairing on yet, so that will probably reduce to 5 smph difference when all is said and done. I cruise at 2400 RPM at 8,500' 55% power burning 24.2 LPH which gives 145 KTAS, and I'm hoping to bring that upto 150 KTAS with a few aerodynamic cleanups later this year.
Even the Vans guys prefer the -9 for long cross-country flights!
Here's a couple of still-air comparisons from Launceston, the RV-4 with the HW tanks cruising at 150 KTAS (5.5Hr end.) and the RV-9 on the bottom, fitted with 2 x LR tanks cruising at 145 KTAS (for 7.0Hr end).